Crystal structure of trichlorooxo-17-bis[(diphenylphosphoryl)methyl]-4(24),6(10),12(16),18( 22)-tetramethylenedioxy-2,8,14,20-tetrapentylresorcin[4]areneuranium(V ) - dichlorodioxo-17-bis[(diphenylphosphoryl)methyl]-4(24),6(10),12(16),18 (22)- tetramethylenedioxy-2,8,14,20-tetrapentylresorcin[4]areneuranium(VI) - hexane (1:3:3), UCl3O(C78H86O10P2)center dot 3UCl(2)O(2)(C78H86O10P2)center dot 3C(6)H(14)

Hani El Moll (1) , David Semeril (2) , Dominique Matt (1) , Loic Toupet (3)

1 Institut de Chimie de Strasbourg
2 Institut de Chimie de Strasbourg
3 GMCM - Groupe matière condensée et matériaux

Ci(65)H(193)CL(4.36)O(23.64)P(4)U(2), triclinic, P (1) over bar (no. 2), a = 15.495(1) angstrom, b = 18.855(2) angstrom, c =30.532(3) angstrom, alpha = 90.717(9)degrees, beta = 101.253(7)degrees, gamma = 109.575(9)degrees, V = 8213.9 angstrom(3), Z = 2, R-gt(F)= 0.055, wR(ref)(F-2)= 0.152, T= 110 K.

Domaines: Physique Générale [physics.gen-ph]

Hani El Moll, David Semeril, Dominique Matt, Loic Toupet. Crystal structure of trichlorooxo-17-bis[(diphenylphosphoryl)methyl]-4(24),6(10),12(16),18( 22)-tetramethylenedioxy-2,8,14,20-tetrapentylresorcin[4]areneuranium(V ) - dichlorodioxo-17-bis[(diphenylphosphoryl)methyl]-4(24),6(10),12(16),18 (22)- tetramethylenedioxy-2,8,14,20-tetrapentylresorcin[4]areneuranium(VI) - hexane (1:3:3), UCl3O(C78H86O10P2)center dot 3UCl(2)O(2)(C78H86O10P2)center dot 3C(6)H(14). Zeitschrift für Kristallographie - New Crystal Structures, 2011, 226 (1), pp.91-96. ⟨10.1524/ncrs.2011.0044⟩. ⟨hal-01068824⟩