The H2O content of granite embryos
Résumé
QuantificationofH2Ocontentsofnaturalgraniteshasbeenanon-goingchallengeowingtotheextremelyfugitivecharacterofH2Oduringcoolingandascentofmeltsandmagmas.Hereweapproachthisproblembystudyinggranitesintheirsourceregion(i.e.thepartiallymeltedcontinentalcrust)andwepresentthefirstNanoSIMSanalysesofanatecticmeltinclusions(MI)hostedinperitecticphasesofmigmatitesandgranulites.TheseMIwhichtotallycrystallizeduponslowcoolingrepresenttheembryosoftheupper-crustalgranites.TheapproachbasedonthecombinationofMIandNanoSIMShasbeenheretestedonamphibolite-faciesmigmatitesatRonda(SSpain)thatunderwentfluid-presenttofluid-absentmeltingat∼700◦Cand∼5kbar.Small( 5μm)crystallizedMItrappedingarnethavebeenremeltedusingapiston-cylinderapparatusandtheyshowleucograniticcompositions.WemeasurehighandvariableH2Ocontents(meanof6.5±1.4wt%)intheselow-temperature,low-pressuregraniticmelts.Wedemonstratethat,whentheentirepopulationfromthesamehostisconsidered,MIrevealtheH2Ocontentofmeltinthespecificvolumeofrockwherethehostgarnetgrew.MeanH2OvaluesfortheMIindifferenthostcrystalsrangefrom5.4to9.1wt%.ThisrangeisinrathergoodagreementwithexperimentalmodelsforgraniticmeltsattheinferredP-Tconditions.OurstudydocumentsforthefirsttimetheoccurrenceofH2Oheterogeneitiesinnaturalgraniticmeltsatthesourceregion.Theseheterogeneitiesareinterpretedtoreflectthebirthofgraniticmeltsunderconditionsof"mosaic"equilibrium,wherethedistinctfractionsofmeltexperiencedifferentbufferingassemblagesatthemicro-scale,withconcomitantdifferencesinmeltH2Ocontent.Theseresultsconfirmtheneedforsmall-scalegeochemicalstudiesonnaturalsamplestoimproveourquantitativeunderstandingofcrustalmeltingandgraniteformation.ThesameapproachadoptedherecanbeappliedtoMIhostedinhigher-temperature,granulite-faciesrocksthatrepresenttheparentsofmanyupper-crustalgranites.Thiswillresultinabetterunderstandingofformationandevolutionofgraniticmagmas.