High-nuclearity, mixed-valence Mn-17, Mn-18 and {Mn-62}(n) complexes from the use of triethanolamine

Theocharis C. Stamatalos , D. Foguet-Albiol , Wolfgang Wernsdorfer (1) , Khalil A. Abboud , George Christou (2)

1 NEEL - QuantECA - Circuits électroniques quantiques Alpes
2 UF|Chemistry - Department of Chemistry [Gainesville]

The use of both azide and triethanolamine, with or without the presence of carboxylate groups, has provided new Mn-17, Mn-18 and {Mn-62}(n) complexes with aesthetically-pleasing cage, layered, and linked-chain-type structures; two are also new single-molecule magnets.

Domaines: Physique [physics]

Theocharis C. Stamatalos, D. Foguet-Albiol, Wolfgang Wernsdorfer, Khalil A. Abboud, George Christou. High-nuclearity, mixed-valence Mn-17, Mn-18 and {Mn-62}(n) complexes from the use of triethanolamine. Chemical Communications, 2011, 47 (1), pp.274-276. ⟨10.1039/c0cc01701a⟩. ⟨hal-00978701⟩