A Mn36Ni4 'loop-of-loops-and-supertetrahedra' aggregate possessing a high S-T=26 +/- 1 spin ground state

Maria Charalambous , Eleni E. Moushi , Constantina Papatriantafyllopoulou , Wolfgang Wernsdorfer (1) , Vassilios Nastopoulos (2) , George Christou (3) , Anastasios J. Tasiopoulos

1 NEEL - QuantECA - Circuits électroniques quantiques Alpes
2 Department of Chemistry
3 UF|Chemistry - Department of Chemistry [Gainesville]

The initial use of 1,3-propanediol in mixed Mn/3d cluster chemistry has led to a (Mn28Mn8Ni4II)-Mn-III-Ni-II molecular aggregate which consists of two (Mn8Ni2)-Ni-III loops and two (Mn6Mn4II)-Mn-III supertetrahedral units and displays a high ground spin state value S-T = 26 +/- 1.

Domaines: Physique [physics]

Maria Charalambous, Eleni E. Moushi, Constantina Papatriantafyllopoulou, Wolfgang Wernsdorfer, Vassilios Nastopoulos, et al.. A Mn36Ni4 'loop-of-loops-and-supertetrahedra' aggregate possessing a high S-T=26 +/- 1 spin ground state. Chemical Communications, 2012, 48 (44), pp.5410-5412. ⟨10.1039/C2CC30654A⟩. ⟨hal-00975519⟩