Steric-Induced Effects on Stabilizing a Lamellar Structure

Barbara B. Gerbelli (1) , Rafael L. Rubim (1) , Emerson R. Silva (1) , Frédéric Nallet (2) , Laurence Navailles (2) , Cristiano L. P. Oliveira (1) , Elisabeth A. de Oliveira (1)

1 Instituto de Fisica
2 CRPP - Centre de recherches Paul Pascal

We investigate the behavior of multilamellar phases composed of lecithin and a commercial cosurfactant (Simusol), which is a mixture of ethoxylated fatty acids. Using X-ray scattering and a new procedure to fit the data, relevant parameters characterizing the lamellar structure were determined as a function of membrane composition, varying from 100% of lecithin to 100% of Simulsol. Scattering data illustrating the swelling of the lamellae for different amounts of cosurfactant are presented with the respective behavior of the Caillé parameter. With this experimental approach, we show that the incorporation of ethoxy brushes onto the lipid surface enhances repulsive interactions arising from membrane fluctuations and changes the interactions at the interface between bilayers.

Barbara B. Gerbelli, Rafael L. Rubim, Emerson R. Silva, Frédéric Nallet, Laurence Navailles, et al.. Steric-Induced Effects on Stabilizing a Lamellar Structure. Langmuir, 2013, 29, pp. 13717-13722. ⟨10.1021/la402962c⟩. ⟨hal-00905406⟩