Preparation and investigation of high purity Ge-Te-AgI glasses for optical application

Vladimir S. Shiryaev (1) , Alexander P. Velmuzhov (1) , Mikhail F. Churbanov (1) , Aleksandr Dmitrievich Plekhovich (1) , Catherine Boussard-Plédel (2) , Johann Troles (2) , Clément Conseil (2) , Victor G. Plotnichenko (3)

1 Institute of Chemistry of High-Purity Substances
2 ISCR - Institut des Sciences Chimiques de Rennes
3 Fiber Optics Research Center

The method for the preparation of high purity Ge-Te-AgI glasses with low content of the limiting impurities has been developed. The method includes the synthesis of GeTe4 glass using chemical distillation purification, loading AgI and GeTe4 into silica glass reactor by evaporation in all-sealed glass vacuumed system, melting the (GeTe4)100 − x(AgI)x (x = 0-20) glass into muffle rocking furnace at 850 °С, quenching the glass in water with subsequent annealing and cooling. The prepared glass samples were investigated by energy-dispersive X-ray microanalysis, DSC, FTIR-spectroscopy, Raman spectroscopy, and laser calorimetry. The high purity (GeTe4)100 − x(AgI)x (x = 0-20) glass samples are characterized by good transparency in the spectral range of 2-20 μm, glass transition temperature of 140-160 °С, Tc − Tg difference of more than 100 °С, and a very low content of the limiting impurities. Some glass compositions with AgI content between 10 and 20 at.% manifest a good thermal stability against crystallization.

Mots clés: Tellurium based chalcogenide glasses; Chemical-distillation purification; Infrared transmission; Crystallization

Domaines: Matériaux

Vladimir S. Shiryaev, Alexander P. Velmuzhov, Mikhail F. Churbanov, Aleksandr Dmitrievich Plekhovich, Catherine Boussard-Plédel, et al.. Preparation and investigation of high purity Ge-Te-AgI glasses for optical application. Journal of Non-Crystalline Solids, 2013, 377, pp.1-7. ⟨10.1016/j.jnoncrysol.2013.03.039⟩. ⟨hal-00860188⟩