Preparation and modification of carbon nanotubes electrodes by cold plasmas processes toward the preparation of amperometric biosensors

E. Luais (1, 2, 3) , C. Thobie-Gautier (1) , A. Tailleur (2) , M. A. Djouadi (2) , Agnès A. Granier (2) , Pierre-Yves Tessier (2) , Dominique Debarnot (3) , Fabienne Poncin-Epaillard (3) , M. Boujtita (1)

1 CEISAM - Chimie Et Interdisciplinarité : Synthèse, Analyse, Modélisation
2 IMN - Institut des Matériaux Jean Rouxel
3 PCI - Polymères, colloïdes, interfaces

An electrochemical transducer based on vertically aligned carbon nanotubes (CNT) was prepared as a platform for biosensor development. Prior to enzyme immobilization, the CNT were treated using a microwave plasma system (CO2 and N2/H2) in order to functionalize the CNT surface with oxygenated and aminated groups. The morphological aspect of the electrode surface was examined by SEM and its chemical structure was also elucidated by XPS analysis. It was found out that microwave plasma system (CO2 and N2/H2) not only functionalizes the CNT but also permits to avoid the collapse phenomena retaining thus the alignment structure of the electrode surface. The electrochemical properties of the resulting new material based on CNT were carried out by cyclic voltammetry and were found suitable to develop high sensitive enzyme (HRP) biosensors operating on direct electron transfer process.

Mots clés: Carbon nanotubes; CNTs’ collapse; Plasma treatment; Direct electron transfer; HRP

Domaines: Science des matériaux [cond-mat.mtrl-sci]

E. Luais, C. Thobie-Gautier, A. Tailleur, M. A. Djouadi, Agnès A. Granier, et al.. Preparation and modification of carbon nanotubes electrodes by cold plasmas processes toward the preparation of amperometric biosensors. Electrochimica Acta, 2010, 55 (27), pp.7916-7922. ⟨10.1016/j.electacta.2010.02.070⟩. ⟨hal-00848884⟩