Hydrogenation of solid hydrogen cyanide HCN and methanimine CH2NH at low temperature

Patrice Theulé (1) , Fabien Borget (1) , Florent Mispelaer (1) , Grégoire Danger (1) , Fabrice Duvernay (1) , Jean-Claude Guillemin (2) , Thierry Chiavassa (1)

1 PIIM - Physique des interactions ioniques et moléculaires
2 ISCR - Institut des Sciences Chimiques de Rennes

Context. Hydrogenation reactions dominate grain surface chemistry in dense molecular clouds and lead to the formation of complex saturated molecules in the interstellar medium. Aims. We investigate in the laboratory the hydrogenation reaction network of hydrogen cyanide HCN. Methods. Pure hydrogen cyanide HCN and methanimine CH2NH ices are bombarded at room temperature by H-atoms in an ultra-high vacuum experiment. Warm H-atoms are generated in an H2 plasma source. The ices are monitored with Fourier-transform infrared spectroscopy in reflection absorption mode. The hydrogenation products are detected in the gas phase by mass spectroscopy during temperature-programmed desorption experiments. Results. HCN hydrogenation leads to the formation of methylamine CH3NH2, and CH2NH hydrogenation leads to the formation of methylamine CH3NH2, suggesting that CH2NH can be a hydrogenation-intermediate species between HCN and CH3NH2. Conclusions. In cold environments the HCN hydrogenation reaction can produce CH3NH2, which is known to be a glycine precursor, and to destroy solid-state HCN, preventing its observation in molecular clouds ices.

Mots clés: astrochemistry; ISM: molecules; molecular processes

Domaines: Chimie théorique et/ou physique

Patrice Theulé, Fabien Borget, Florent Mispelaer, Grégoire Danger, Fabrice Duvernay, et al.. Hydrogenation of solid hydrogen cyanide HCN and methanimine CH2NH at low temperature. Astronomy and Astrophysics - A&A, 2011, 534, pp.A64. ⟨10.1051/0004-6361/201117494⟩. ⟨hal-00844618⟩