Silver-palladium cathode: Selective one-electron scission of alkyl halides: Homo-coupling and cross-coupling subsequent reactions

Philippe Poizot (1) , Jacques Simonet (2)

1 LRCS - Laboratoire réactivité et chimie des solides - UMR CNRS 7314
2 ISCR - Institut des Sciences Chimiques de Rennes

The formation of silver-palladium electrodes is described. It mainly corresponds to the palladization of silver by means of treatment with palladium salts (nitrate and sulphate) in acidic media. Other ways may exist such as the modification of solid conductors like carbons by deposition of a silver-palladium alloy. By using those electrodes in polar aprotic solvents, the one-electron cleavage of carbon-halogen bonds of most alkyl iodides and bromides may yield free alkyl radicals. Coupling and cross-coupling reactions can easily be carried out at such electrodes. The present review aims at discussing the electro-catalytic process as well as providing an update on the state of the art on this new mode of scission regarding carbon-heteroatom bonds.

Mots clés: Silver-palladium electrode; Carbon-halogen bonds; Cathodic bond cleavages; Alkyl radicals

Domaines: Matériaux

Philippe Poizot, Jacques Simonet. Silver-palladium cathode: Selective one-electron scission of alkyl halides: Homo-coupling and cross-coupling subsequent reactions. Electrochimica Acta, 2010, 56 (1), pp.15-36. ⟨10.1016/j.electacta.2010.09.020⟩. ⟨hal-00840067⟩