Suspension plasma sprayed bioactive glass coatings: Effects of processing on microstructure, mechanical properties and in-vitro behaviour

Andrea Cattini (1) , Leszek Latka (1) , D. Bellucci (2) , G. Bolelli (2) , A. Sola (2) , L. Lusvarghi (2) , Lech Pawlowski (1) , Valeria Cannillo (2)

1 Axe 2 : procédés de traitements de surface
2 Department of Materials and Environmental Engineering

Bioactive glass coatings deposited via suspension plasma sprayingwere studied to improve the adhesion between orthopaedic implants and bone. Fine powders of a bioactive glass, named BG_Ca, having composition (in wt.%): 4.7 Na2O, 42.3 CaO, 6.1 P2O5, and 46.9 SiO2, were produced and dispersed in ethanol to form a suspension used as a feedstock. Various sets of spray parameterswere applied in order to define the influence of the deposition process on the final coating properties. Consequently, the coatings were characterized in as-sprayed state and after soaking in a simulated body fluid (SBF) for different periods ranging from 1 to 14 days. Themicrostructural investigationswere carried out using environmental scanning electronmicroscope (ESEM) and X-ray diffraction (XRD). The coatings' adhesion to the substrate was evaluated bymeans of scratch tests. Finally, hardness and elasticmodulus were determined by means of depth-sensing indentation methods.

Mots clés: Bioactive glass Suspension plasma spray Simulated body fluid Scratch test Depth-sensing indentation

Andrea Cattini, Leszek Latka, D. Bellucci, G. Bolelli, A. Sola, et al.. Suspension plasma sprayed bioactive glass coatings: Effects of processing on microstructure, mechanical properties and in-vitro behaviour. Surface and Coatings Technology, 2013, 220, pp.52-59. ⟨10.1016/j.surfcoat.2012.10.076⟩. ⟨hal-00809178⟩