A μ9-iodide in a tricapped trigonal-prismatic geometry.

Yi-Juan Li , Camille Latouche (1) , Samia Kahlal (1) , Jian-Hong Liao , Rajendra Singh Dhayal , Jean-Yves Saillard (1) , C. W. Liu

1 ISCR - Institut des Sciences Chimiques de Rennes

Two luminescent, undecanuclear silver complexes [Ag(11)(μ(9)-I)(μ(3)-I)(3){E(2)P(O(i)Pr)(2)}(6)](PF(6)) [E = S (yellow), 1; Se (orange), 2], containing the first μ(9)-iodine inscribed at the center of a pentacapped trigonal-prismatic silver skeleton, were reported.

Domaines: Chimie théorique et/ou physique

Yi-Juan Li, Camille Latouche, Samia Kahlal, Jian-Hong Liao, Rajendra Singh Dhayal, et al.. A μ9-iodide in a tricapped trigonal-prismatic geometry.. Inorganic Chemistry, 2012, 51 (14), pp.7439-41. ⟨10.1021/ic3007475⟩. ⟨hal-00753722⟩