Tailoring metal-organic framework catalysts by click chemistry

M. Savonnet , A. Camarata (1) , J. Canivet (1) , Delphine Bazer-Bachi , Nicolas Bats , V. Lecocq , C. Pinel (2) , D. Farrusseng (1)

1 INGENIERIE - INGENIERIE
2 BIOVERT - BIOVERT

We successively introduce new catalytic centers through click reaction into MOFs and modify their environment by addition of lipophilic groups. The resulting bifunctionalized MOF provides an optimized balance between basicity and lipophilicity and shows outstanding performance for the transesterification reaction.

Domaines: Catalyse; Environnement et Société

M. Savonnet, A. Camarata, J. Canivet, Delphine Bazer-Bachi, Nicolas Bats, et al.. Tailoring metal-organic framework catalysts by click chemistry. Dalton Transactions, 2012, 41, pp.3945-3948. ⟨10.1039/c2dt11994c⟩. ⟨hal-00700212⟩