Breathing transitions in MIL-53(Al) metal-organic framework upon xenon adsorption.

Abstract : MOFs come alive: The combination of gas‐adsorption experiments at various temperatures with an osmotic thermodynamic model produced a generic temperature–loading phase diagram that displays unexpected re‐entrant behavior. The breathing effect in the metal–organic framework MIL‐53(Al) is predicted to be general and should be observed over a limited temperature range regardless of the guest adsorbate.
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Submitted on : Wednesday, May 1, 2019 - 5:34:45 PM
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Anne Boutin, Marie-Anne Springuel-Huet, Andrei Nossov, Antoine Gedeon, Thierry Loiseau, et al.. Breathing transitions in MIL-53(Al) metal-organic framework upon xenon adsorption.. Angewandte Chemie (English Edition), John Wiley & Sons, 2009, 48 (44), pp.8314-7. ⟨10.1002/anie.200903153⟩. ⟨hal-00548070⟩

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