Exceptional Sensitivity of Metal-Aryl Bond Energies to ortho-Fluorine Substituents: Influence of the Metal, the Coordination Sphere, and the Spectator Ligands on M-C/H-C Bond Energy Correlations.

Eric Clot (1) , Claire Mégret (1) , Odile Eisenstein (1) , Robin N. Perutz (2)

1 ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier
2 Department of Chemistry [York, UK]

Domaines: Chimie-Physique [physics.chem-ph]

Eric Clot, Claire Mégret, Odile Eisenstein, Robin N. Perutz. Exceptional Sensitivity of Metal-Aryl Bond Energies to ortho-Fluorine Substituents: Influence of the Metal, the Coordination Sphere, and the Spectator Ligands on M-C/H-C Bond Energy Correlations.. Journal of the American Chemical Society, 2009, 131, pp.7817-7827. ⟨10.1021/ja901640m⟩. ⟨hal-00391067⟩