Hyperbolic models in gas-solid chromatography

Christian Bourdarias (1) , Marguerite Gisclon (1) , Stéphane Junca (2)

1 LAMA - Laboratoire de Mathématiques
2 JAD - Laboratoire Jean Alexandre Dieudonné

We present different models arising in chemical engineering and essentially related to isothermal gas chromatography. These models describe a fixed bed adsorption process of separation of a gaseous mixture: each compound can exist either in a mobile phase or a solid and static one, with a finite or infinite mass-exchange kinetics. Many authors, in the fields of chemical engineering and mathematics, have investigated these models under various assumptions, from a theoretical or numerical point of view. We explain first the relations between some of these approaches. Next, we present some results related to these models, some of them being new, particularly in the case of a monovariant system with one or two active compounds for the Cauchy problem. Lastly, we mention some open problems.

Mots clés: systems of conservation laws; adsorption; nonlinear chromatography; mass transfer kinetics; gas chromatography

Domaines: Equations aux dérivées partielles [math.AP]; Génie chimique

Christian Bourdarias, Marguerite Gisclon, Stéphane Junca. Hyperbolic models in gas-solid chromatography. SeMA Journal: Boletin de la Sociedad Española de Matemática Aplicada, 2008, 43, pp.29-57. ⟨hal-00387202⟩