Experimental and DFT studies of cationic imido titanium alkyls: Agostic interactions and C-H bond and solvent activation reactions of isolobal analogues of group 4 metallocenium cations

Paul D. Bolton (1) , Eric Clot (2) , Nico Adams (1) , Stuart R. Dubberley (1) , Andrew R. Cowley (1) , Philip Mountford (1)

1 Chemistry Research Laboratory
2 ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier

Domaines: Chimie-Physique [physics.chem-ph]

Paul D. Bolton, Eric Clot, Nico Adams, Stuart R. Dubberley, Andrew R. Cowley, et al.. Experimental and DFT studies of cationic imido titanium alkyls: Agostic interactions and C-H bond and solvent activation reactions of isolobal analogues of group 4 metallocenium cations. Organometallics, 2006, 25, pp.2806-2825. ⟨10.1021/om060096r⟩. ⟨hal-00362463⟩