Unsteady rheometry: Can we characterize weak gels with a controlled stress rheometer?
Résumé
This paper is concerned with the influence of apparatus inertia effects in controlled stress rheometry. As evidenced on creep experiments, the coexistence of apparatus inertia and viscoelasticity leads to a coupling frequency. For weak gels, this coupling frequency is typically between 1 and 100 Hz. Therefore, frequency sweeps around and above this coupling frequency also corresponds to an effective shear stress sweep evolution due to a non-trivial resonant effect. In other words, frequency sweep experiments are not made at constant shear stress. The detailed modelling and analysis of this inertia effect on a typical weak gel shows a clear and fundamental limitation for its characterization using a controlled stress rheometer. Also, alternative approaches to standard rheometer software analysis are proposed to take this coupling effect into account.