Nanocrystalline Metal Oxides from the Injection of Metal Oxide Sols in Coordinating Solutions: Synthesis, Characterization, Thermal Stabilization, Device Processing, and Gas-Sensing Properties - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Advanced Functional Materials Année : 2006

Nanocrystalline Metal Oxides from the Injection of Metal Oxide Sols in Coordinating Solutions: Synthesis, Characterization, Thermal Stabilization, Device Processing, and Gas-Sensing Properties

Résumé

Metal oxide (SnO2, TiO2, In2O3, ZnO) sols are prepared by various sol-gel processes in such a way as to hinder the condensation reactions. The obtained sols are injected at 160 °C into a solution of tetradecene and dodecylamine, and kept under heating for different periods of time. Depending on the starting sol, variously crystallized oxide nanoparticles are obtained, whose phase compositions and chemical structure have been studied by X-ray diffraction (XRD) and Fourier transform IR spectroscopy. The elimination of the organic residuals has been carried out by thermal treatment, and the thermal evolution of the nanoparticles has been studied by thermal analyses and Raman spectroscopy. High-resolution transmission electron microscopy studies coupled with XRD measurements show that the thermal treatment does not markedly affect the particle size, which remains in the nanometer-sized regime (from 3.5 to 8.5 nm, depending on the system), except in the case of ZnO. The thermally purified and stabilized powders, drop-coated onto alumina substrates with pre-deposited electrical contacts, have been tested as gas-sensing devices, displaying outstanding sensing properties even at room temperature.

Domaines

Matériaux

Dates et versions

hal-00333280 , version 1 (22-10-2008)

Identifiants

Citer

Mauro Epifani, Raül Díaz, Jordi Arbiol, Elisabetta Comini, Nicolas Sergent, et al.. Nanocrystalline Metal Oxides from the Injection of Metal Oxide Sols in Coordinating Solutions: Synthesis, Characterization, Thermal Stabilization, Device Processing, and Gas-Sensing Properties. Advanced Functional Materials, 2006, 16 (11), pp. 1488-1498. ⟨10.1002/adfm.200500652⟩. ⟨hal-00333280⟩
71 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More