Impact of the new HNO3-forming channel of the HO2+NO reaction on tropospheric HNO3, NOx, HOx and ozone

D. Cariolle 1, 2 M. J. Evans 3 M. P. Chipperfield 3 N. Butkovskaya 4 A. Kukui 5 G. Le Bras 4
1 CERFACS - Centre Européen de Recherche et de Formation Avancée en Calcul Scientifique
2 Météo-France [Paris]
3 Institute for Atmospheric Science [Leeds]
4 ICARE - Institut de Combustion, Aérothermique, Réactivité et Environnement
5 SA - Service d'aéronomie
Abstract : We have studied the impact of the recently established reaction NO+HO2?HNO3 on atmospheric chemistry. A pressure and temperature-dependent parameterisation of this minor channel of the NO+HO2?NO2+OH reaction has been included in both a 2-D stratosphere-troposphere model and a 3-D tropospheric chemical transport model (CTM). Significant effects on the nitrogen species and hydroxyl radical concentrations are found throughout the troposphere, with the largest percentage changes occurring in the tropical upper troposphere (UT). Including the reaction leads to a reduction in NOx everywhere in the troposphere, with the largest decrease of 25% in the tropical and southern hemisphere UT. The tropical UT also has a corresponding large increase in HNO3 of 25%. OH decreases throughout the troposphere with the largest reduction of over 20% in the tropical UT. Mean global decreases in OH are around 13% which leads to a increase in CH4 lifetime of 5%. Due to the impact of decreased NOx on the OH:HO2 partitioning, modelled HO2 actually increases in the tropical UT on including the new reaction. The impact on tropospheric ozone is a decrease in the range 5 to 12%, with the largest impact in the tropics and southern hemisphere. Comparison with observations shows that in the region of largest changes, i.e. the tropical UT, the inclusion of the new reaction tends to degrade the model agreement. Elsewhere the model comparisons are not able to critically assess the impact of including this reaction. Only small changes are calculated in the minor species distributions in the stratosphere.
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D. Cariolle, M. J. Evans, M. P. Chipperfield, N. Butkovskaya, A. Kukui, et al.. Impact of the new HNO3-forming channel of the HO2+NO reaction on tropospheric HNO3, NOx, HOx and ozone. Atmospheric Chemistry and Physics Discussions, European Geosciences Union, 2008, 8 (1), pp.2695-2713. ⟨hal-00328303⟩

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