Improved stability of redox enzyme layers on glassy carbon electrodes via covalent grafting

Marie Pellissier (1) , Frédéric Barrière (1) , Alison J. Downard (2) , Donal Leech (3)

1 ISCR - Institut des Sciences Chimiques de Rennes
2 MacDiarmid Institute for Advanced Materials and Nanotechnology
3 Departement of Chemistry, Galway

One of the challenges in the field of enzymatic biofuel cells is to significantly improve their current limited lifetime. In the present work, we report the covalent immobilization of enzyme layers on glassy carbon electrodes, functionalized via electrochemical reduction of insitu generated aryldiazonium salts bearing carboxylic acid groups. We present the performance and the stability over time of the modified electrodes. For glucose oxidase - modified electrodes, stable catalytic activity is observed for a minimum of 6 weeks.

Mots clés: Aryldiazonium reduction; Surface modification; Enzyme layers; Stability; Glucose oxidase; Redox mediators

Domaines: Autre

Marie Pellissier, Frédéric Barrière, Alison J. Downard, Donal Leech. Improved stability of redox enzyme layers on glassy carbon electrodes via covalent grafting. Electrochemistry Communications, 2008, 10 (6), pp.835-838. ⟨10.1016/j.elecom.2008.03.010⟩. ⟨hal-00283499⟩