Stereochemical nonrigidity of a chiral rhodium boryl hydride complex: a σ-borane complexe as transition state for isomerization.

Marius V. Campian (1) , Eric Clot (2) , Odile Eisenstein (2) , Ulrike Helmstedt (2) , Naseralla Jasim (1) , Robin N. Perutz (1) , Adrian C. Whitwood (1) , David Williamson (1)

1 Department of Chemistry [York, UK]
2 ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier

Domaines: Chimie-Physique [physics.chem-ph]

Marius V. Campian, Eric Clot, Odile Eisenstein, Ulrike Helmstedt, Naseralla Jasim, et al.. Stereochemical nonrigidity of a chiral rhodium boryl hydride complex: a σ-borane complexe as transition state for isomerization.. Journal of the American Chemical Society, 2008, 130, pp.4375-4385. ⟨10.1021/ja077357o⟩. ⟨hal-00267313⟩