Dendritic stars by ring-opening-metathesis polymerization from ruthenium-carbene initiators

Sylvain Gatard (1) , Sylvain Nlate (1) , Eric Cloutet (2) , Georges Bravic (3) , Jean-Claude Blais (4) , Didier Astruc (1)

1 LCOO - Laboratoire de chimie organique et organométallique
2 LCPO - Laboratoire de Chimie des polymères organiques
3 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux
4 CSOB - Chimie Structurale Organique et Biologique

Dendrimers are a rich and appealing field of polymer chemistry. Organic polymerization form dendritic initiators also offers a route to highly branched polymers, and indeed these have been obtained, amongest other methods, ...

Mots clés: Carbenes; Dendrimers; Metathesis; Polymerization; Ruthenium

Domaines: Matériaux; Chimie organique; Polymères

Sylvain Gatard, Sylvain Nlate, Eric Cloutet, Georges Bravic, Jean-Claude Blais, et al.. Dendritic stars by ring-opening-metathesis polymerization from ruthenium-carbene initiators. Angewandte Chemie International Edition, 2003, 42 (4), pp.452-456. ⟨10.1002/anie.200390137⟩. ⟨hal-00258379⟩