Selective catalytic reduction of NO on copper-exchanged zeolites: the role of the structure of the zeolite in the nature of copper-active sites

Cidalia Torre-Abreu (1) , Maria Filipa Ribeiro (1) , Carlos Henriques (1) , Fernando Ramôa Ribeiro (1) , Gerard Delahay (2)

1 Departamento de Engenharia Quimica
2 LMCCCO - Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique

Copper-exchanged zeolites with different structures (CuMFI, CuMOR and CuY) used as catalysts on the selective catalytic reduction (SCR) of NO by propene have been studied. Different types of Cu species were identified (Cu2+, Cu+, and CuO) by H2-TPR and NO TPD. The structure of each zeolite determines the nature and concentration of those species and the catalytic behavior for SCR of NO by propene in the presence of oxygen. A correlation was observed between the catalytic activity, and the presence of isolated Cu2+ species, which is enhanced by MFI structure.

Mots clés: Copper-exchanged zeolite; CuMFI; CuMOR; CuY; NO; Selective catalytic reduction (SCR); NO TPD; H2-TPR

Domaines: Catalyse

Cidalia Torre-Abreu, Maria Filipa Ribeiro, Carlos Henriques, Fernando Ramôa Ribeiro, Gerard Delahay. Selective catalytic reduction of NO on copper-exchanged zeolites: the role of the structure of the zeolite in the nature of copper-active sites. Catalysis Today, 1999, 54, pp.407-418. ⟨10.1016/S0920-5861(99)00204-7⟩. ⟨hal-00178956⟩