Structural Rearrangements Induced by Photoexcitation in a RbCoFe Prussian Blue Derivative

Christophe Cartier Dit Moulin , Guillaume Champion , Jean-Daniel Cafun , Marie-Anne Arrio (1) , Anne Bleuzen

1 IMPMC - Institut de minéralogie et de physique des milieux condensés

Systems that undergo a reversible and controlled change of their physical properties offer appealing perspectives for the elaboration of electronic devices. Evidence of a photomag- netic effect in a CoFe Prussian blue analogue was a milestone in this research area and showed that molecular excitation can induce long-range magnetic order.[1] In the face-centered cubic structure of the CoFe Prussian blue analogues of chemical formula MxCo4[Fe(CN)6](8+x)/3&(4

Domaines: Autre [cond-mat.other]

Christophe Cartier Dit Moulin, Guillaume Champion, Jean-Daniel Cafun, Marie-Anne Arrio, Anne Bleuzen. Structural Rearrangements Induced by Photoexcitation in a RbCoFe Prussian Blue Derivative. Angewandte Chemie, 2007, 46, pp.1287-1289. ⟨10.1002/anie.200603829⟩. ⟨hal-00172585⟩