A new 1D hybrid fluoroaluminate templated by an original tetramine

Karim Adil (1, 2) , Armel Le Bail (1, 2) , Gilles Dujardin (3, 2) , Vincent Maisonneuve (1, 2)

1 LdOF - Laboratoire des oxydes et fluorures
2 IRIMMFUM - Institut de recherche en ingénierie moléculaire et matériaux fonctionnels de l'université du Maine
3 UCO2M - Unité de chimie organique moléculaire et macromoléculaire

An original polyamine, 2,3 di-2-aminomethyl 1,4 diaminobut-2-ene (ten), characterized by single-crystal XRD analysis, has been synthesised and leads to a new hybrid fluoroaluminate [H4ten] · (AlF5)2 by microwave heating assisted hydrothermal synthesis. The structure of [H4ten] · (AlF5)2 is ab initio determined from powder data.

Mots clés: Hydrothermal synthesis; Hybrid fluoride; Aluminate; Organic template; Tetramine

Domaines: Chimie organique

Karim Adil, Armel Le Bail, Gilles Dujardin, Vincent Maisonneuve. A new 1D hybrid fluoroaluminate templated by an original tetramine. Polyhedron, 2007, 26 (12), pp.2493-2497. ⟨hal-00159999⟩