Chemical bonding differences evidenced from J-coupling in solid state NMR experiments involving quadrupolar nuclei

Dominique Massiot (1) , Franck Fayon (1) , Bruno Alonso (1) , Julien Trébosc (2) , Jean-Paul Amoureux (2)

1 CRMHT - Centre de recherches sur les matériaux à haute température
2 LCPS - Laboratoire de cristallochimie et physicochimie du solide

Small scalar J-coupling between quadrupolar nuclei and spin 1/2 can be measured in inorganic solids using J-Resolved experiments and further used to acquire 2D J-HQMC heteronuclear correlation, giving detailed insight into the chemical bonding scheme.

Domaines: Autre; Matériaux

Dominique Massiot, Franck Fayon, Bruno Alonso, Julien Trébosc, Jean-Paul Amoureux. Chemical bonding differences evidenced from J-coupling in solid state NMR experiments involving quadrupolar nuclei. Journal of Magnetic Resonance, 2003, 164, pp.160-164. ⟨10.1016/S1090-7807(03)00134-4⟩. ⟨hal-00107193⟩