Very large ising-type magnetic anisotropy in a mononuclear Ni-II complex

Guillaume Rogez (1, 2) , Jean-Nöel Rebilly (1) , Anne-Laure Barra (3) , Lorenzo Sorace (4) , Geneviève Blondin (1) , Nadeschda Kirchner (5) , Marc Duran (5) , Joris van Slageren (5) , Simon Parsons (6) , Louis Ricard (7) , Arnaud Marvilliers (1) , Talal Mallah (1)

1 LCI - Laboratoire de chimie inorganique
2 IPCMS - Institut de Physique et Chimie des Matériaux de Strasbourg
3 LCMI-GHMFL - Laboratoire des champs magnétiques intenses
4 UdR INSTM and Department of Chemistry
5 1. Physikalisches Institut [Stuttgart]
6 Department of Chemistry
7 DCPH - Laboratoire Hétéroéléments et Coordination

Mots clés: Angular-overlap model; EPR spectroscopy; FDMR spectroscopy; magnetic properties; nickel

Domaines: Chimie de coordination

Guillaume Rogez, Jean-Nöel Rebilly, Anne-Laure Barra, Lorenzo Sorace, Geneviève Blondin, et al.. Very large ising-type magnetic anisotropy in a mononuclear Ni-II complex. Angewandte Chemie International Edition, 2005, 44, pp.1876. ⟨10.1002/anie.200462294⟩. ⟨hal-00087292⟩