Ca and Na environments in Na2O–CaO–Al2O3–SiO2 glasses: influence of cation mixing and cation-network interactions.

L. Cormier (1) , D.R. Neuville (2)

1 IMPMC - Institut de minéralogie et de physique des milieux condensés
2 IPGP - Institut de Physique du Globe de Paris

X-ray absorption spectroscopy at Ca and Na K-edges and Molecular Dynamics (MD) simulations are used to investigate the Ca and Na environment in soda lime aluminosilicate glasses. Both X-ray Absorption Near Edge Structure (XANES) spectra and MD calculations indicate a coordination number of about 7 for Ca and 6 for Na, in a distorted polyhedron. Ca and Na XANES spectra are poorly affected either by the Si/Al substitution or the Ca/Na substitution while MD simulations present some variations in the cationic environment. We show an affinity for non-bridging oxygens (NBOs) to be connected with Ca rather than Na. Evidence of Ca–Na mixing is shown by the MD models and there is a tendency toward forming more regions enriched in (Ca, NBOs) for CaO-rich aluminosilicate glasses. Variations in the cationic mobility upon the Na/Ca substitution are correlated with the observed structural modifications.

Mots clés: Na2O–CaO–Al2O3–SiO2 glasses; XANES; Molecular Dynamics

L. Cormier, D.R. Neuville. Ca and Na environments in Na2O–CaO–Al2O3–SiO2 glasses: influence of cation mixing and cation-network interactions.. Chemical Geology, 2004, 213, pp.103-113. ⟨10.1016/j.chemgeo.2004.08.049⟩. ⟨hal-00086748⟩