Archimedean Tilings and Hierarchical Lamellar Morphology Formed by Semicrystalline Miktoarm Star Terpolymer Thin Films

Karim Aissou 1, 2 Wonsang Kwon 1 Muhammad Mumtaz 1, 2 Ségolène Antoine 1, 2 Mireille Maret 3 Giuseppe Portale 4 Guillaume Fleury 1, 2 Georges Hadziioannou 1, 2
1 LCPO - Laboratoire de Chimie des Polymères Organiques
2 TEAM 4 LCPO
3 CNRS IPB, Lab Sci & Ingn Mat & Proc
4 Univ Groningen, Zernike Inst Adv Mat, Macromol Chem & New Polym Mat
Abstract : 3-Miktoarm star terpolymer architecture provides a window of opportunity in the design of complex "three-colored" patterns at the nanometer scale. Here, the directed self-assembly (DSA) of 3-miktoarm star terpolymer (poly(1, 1-dimethyl silacydobutane)-arm-polystyrene-armpoly(D,L-lactide acid)) (PDMSB-arm-PS-arm-PLA, noted hereafter 3 mu-DSL) into a hierarchical lamellar morphology is described. Excellent orientational order has been achieved by templating the asymmetric hierarchical lamellar morphology with topographical substrates. Increasing the PLA volume fraction leads to the formation of a hexagonal [6.6.6] Archimedean tiling which coexists with a metastable square symmetry [4.8.8] tiling stabilized by the step between terraces. Stability of the [6.6.6] tiling over the [4.8.8] one is also demonstrated with GISAXS measurements.
Keywords : POLYMERS POLYSTYRENE TOMOGRAPHY HETEROARM 3-miktoarm star terpolymer directed self-assembly hierarchical lamellar pattern Archimedean tiling topographical substrate SHAPED TERPOLYMERS COPOLYMER SQUARE
Type de document :
Article dans une revue
ACS Nano, American Chemical Society, 2016, 10 (4), pp.4055-4061. 〈10.1021/acsnano.5b06728 〉
Domaine :
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https://hal.archives-ouvertes.fr/hal-01369604
Contributeur : Dominique Richard <>
Soumis le : mercredi 21 septembre 2016 - 11:30:52
Dernière modification le : jeudi 11 janvier 2018 - 06:28:09

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Karim Aissou, Wonsang Kwon, Muhammad Mumtaz, Ségolène Antoine, Mireille Maret, et al.. Archimedean Tilings and Hierarchical Lamellar Morphology Formed by Semicrystalline Miktoarm Star Terpolymer Thin Films . ACS Nano, American Chemical Society, 2016, 10 (4), pp.4055-4061. 〈10.1021/acsnano.5b06728 〉. 〈hal-01369604〉

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