Tuning the composition of rare earth sesquioxides Gd2-xLaxO3:Eu3+ to control phase transitions at a high temperature to design new highly sensitive luminescence-based thermal sensors

Guillaume Salek (1) , Alexis Devoti (1) , Alain Garcia (1) , Manuel Gaudon (1) , Veronique Jubera (1) , Alain Demourgues (1)

1 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux

The C-form (SG: Ia[3 with combining macron]) → B-form (SG: C2/m) phase transition of RE2O3 rare earth sesquioxides is described for the first time for face centred cubic–hexagonal close-packed array transformations. Based on XRD data analysis, the temperature of the C → B phase transition in Gd2−xLaxO3 compositions (0 < x < 0.5) was controlled by adjusting the Gd/La atomic ratio and varies between 1100 °C and 1400 °C. Taking into account the various environments of rare earth oxides in C and B allotropic forms, Eu3+ was used as a local probe to obtain photoluminescence spectra (emission and excitation spectra, luminescence decay time curves). The spectra significantly changed during the phase transition, which occurred within a small temperature range. Furthermore, coupling Rietveld XRD data analysis for the long-range order signature with optical emission spectroscopy to probe the local environment provides a clear view of the C → B phase transition, allowing for the design of new highly sensitive thermal sensors at high temperatures.

Domaines: Matériaux; Chimie inorganique

Guillaume Salek, Alexis Devoti, Alain Garcia, Manuel Gaudon, Veronique Jubera, et al.. Tuning the composition of rare earth sesquioxides Gd2-xLaxO3:Eu3+ to control phase transitions at a high temperature to design new highly sensitive luminescence-based thermal sensors. RSC Advances, 2016, 6 (60), pp.55298-55306. ⟨10.1039/c6ra07607f⟩. ⟨hal-01343948⟩