Sequential dehydrogenation-arylation of diisopropylamine-borane complex catalyzed by palladium nanoparticles

Hélène Gerrand (1) , Ludovic Marciasini (1) , Thomas Gendrineau (1) , Oana Pascu (2) , Samuel Marre (2) , Sandra Pinet (1) , Michel Vaultier (1) , Cyril Aymonier (2) , Mathieu Pucheault (1)

1 ISM - Institut des Sciences Moléculaires
2 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux

Palladium nanoparticles have been prepared using different techniques, CO2-assisted microfluidics coflow or thermolysis using ionic liquids. Both techniques displayed interesting activities in dehydrogenation of diisopropylamine-borane complex, and allowed performing a dehydrogenation-arylation sequence with the creation of a carbon-boron bond.

Mots clés: Palladium; Nanoparticle; Borane; Catalysis; Borylation

Domaines: Matériaux

Hélène Gerrand, Ludovic Marciasini, Thomas Gendrineau, Oana Pascu, Samuel Marre, et al.. Sequential dehydrogenation-arylation of diisopropylamine-borane complex catalyzed by palladium nanoparticles. Tetrahedron, 2014, 70 (36), pp.6156-6161. ⟨10.1016/j.tet.2014.04.036⟩. ⟨hal-01060909⟩