Metal-ion induced FRET in macrocyclic dynamic tweezers

Stéphanie Delbaere (1) , Elena V. Tulyakova (1) , Emilie Marmois (2) , Gediminas Jonusauskas (2) , Elena N. Gulakova (3) , Yuri V. Fedorov (3) , Olga A. Fedorova (3)

1 LASIRE - Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516
2 LOMA - Laboratoire Ondes et Matière d'Aquitaine
3 INEOS - A. N. Nesmeyanov Institute of Organoelement Compounds

Abstract We report here about effective FRET process (73-99%) in mono-Mg2+ complexes of symmetrical crown ether bis(styryl) dyes. The FRET process has not been observed in the free state and in binuclear complexes. The formation of mononuclear complex provides two styrylic fragments with appropriate positions of absorption and emission bands for FRET. The other important parameter for FRET is the proper geometric orientation of both chromophores, which attain sandwich conformation with close positioning of complexed and free styryl fragments induced by ion-modulated geometry reorganization of the bis-dye.

Mots clés: FRET; Sandwich complex; Binding constants determination; Complex formation; Bis(styryl) dyes; Crown ether

Domaines: Chimie-Physique [physics.chem-ph]; Chimie de coordination

Stéphanie Delbaere, Elena V. Tulyakova, Emilie Marmois, Gediminas Jonusauskas, Elena N. Gulakova, et al.. Metal-ion induced FRET in macrocyclic dynamic tweezers. Tetrahedron, 2013, 69 (38), pp.8178-8185. ⟨10.1016/j.tet.2013.07.042⟩. ⟨hal-00874421⟩