Crystal growth and characterization of tetragonal tungsten bronze FerroNiobates Ba2LnFeNb4O15

Elias Castel (1) , Philippe Veber (2, 3, 1) , Marjorie Albino (1) , Matias Velázquez (1) , Stanislav Pechev (1) , Dominique Denux (1) , Jean-Pierre Chaminade (1) , Mario Maglione (1) , Michaël Josse (1)

1 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux
2 CNRS - Centre National de la Recherche Scientifique
3 UVT - Universitatea de Vest din Timișoara [România] = West University of Timișoara [Romania] = Université Ouest de Timișoara [Roumanie]

Tetragonal Tungsten Bronze Ferroelectrics (TTB) are currently revisited for the elaboration of new multifunctional materials. Recent studies on Ba2LnFeNb4O15 ceramics (Ln=Nd, Sm and Eu) demonstrated that these materials display both ferroelectric and ferromagnetic behaviors at room temperature due to the presence of barium hexaferrite as a secondary phase. In this paper, we report for the first time the growth of Ba2LnFeNb4O15 single crystals (Ln=La, Pr, Nd, Sm and Eu) from high temperature solution using LiBO2 flux. Inclusion free millimeter-sized single crystals were successfully grown. Structural and dielectric characterizations were performed and chemical analysis confirmed that the TTB matrix is reluctant to accommodate small rare earth as it was observed for ceramics. A paramagnetic behavior was observed for all compositions, which corroborates the composite nature of the TTB ceramic multiferroics at room temperature, while dielectric measurements on Ln=La and Pr crystals confirmed their relaxor behavior.

Mots clés: Crystal structure; Growth from high temperature solutions; Tungsten bronzes; Crystal structure

Domaines: Matériaux

Elias Castel, Philippe Veber, Marjorie Albino, Matias Velázquez, Stanislav Pechev, et al.. Crystal growth and characterization of tetragonal tungsten bronze FerroNiobates Ba2LnFeNb4O15. Journal of Crystal Growth, 2012, 340 (1), pp.156-165. ⟨10.1016/j.jcrysgro.2011.11.082⟩. ⟨hal-00664962⟩