Synthesis and spectroscopic characterization of some new oxalate Snph2x (X = Cl, Ncs, Ncse) containing derivatives and adduct

Kochikpa Y. A. Okio (1) , Alioune Fall (1) , Hayat Qamar-Kane (1) , Yaya Sow (1) , Libasse Diop (1) , Lamine A. Diop (2) , Umberto Russo (3) , Alain Wattiaux (4)

1 LACHIMIA - Laboratoire de Chimie Minérale et Analytique
2 Université de Saint-Boniface
3 Dipartimento di Chimica Inorganica Metallorganica ed Analitica
4 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux

Six new oxalato chlorodiorganostannic derivatives and adduct have been synthesized, their infrared andMössbauer studies carried out. Polymeric structures have been suggested, the oxalate behaving as amonochelating or a bichelating donor. R2NH2+ cations, when involved, lead to supramolecular structures.

Mots clés: Oxalato; Chlorodiorganotin (IV) group; Spectroscopy; Infrared; Mössbauer; Polymeric structures; Supramolecular structures

Domaines: Chimie de coordination; Polymères

Kochikpa Y. A. Okio, Alioune Fall, Hayat Qamar-Kane, Yaya Sow, Libasse Diop, et al.. Synthesis and spectroscopic characterization of some new oxalate Snph2x (X = Cl, Ncs, Ncse) containing derivatives and adduct. Main Group Metal Chemistry, 2010, 33 (1), pp.53-58. ⟨10.1515/MGMC.2010.33.1-2.53⟩. ⟨hal-00530067⟩