Some new sulfato and hydrogenosulfato adducts : synthesis, infrared and Mössbauer studies

Waly Diallo (1) , Kochikpa Y. A. Okio (1) , Libasse Diop (1) , Amadou-Lamine Diop (2) , Umberto Russo (3) , Alain Wattiaux (4)

1 LACHIMIA - Laboratoire de Chimie Minérale et Analytique
2 Université de Saint-Boniface
3 Dipartimento di Chimica Inorganica Metallorganica ed Analitica
4 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux

Eight organotin (IV) (mainly sulfato) adducts have been synthesized and studied by spectroscopic methods. While considering the anionic component, the suggested structures are discrete ; supramolecular architectures are obtained with secondary interactions through NH---Cl and NH---O hydrogen bonds while considering the cations, the anions behaving as monochelating, bridging or monocoordinating ligands, the environment...

Mots clés: Organotin (IV) adducts; Infrared; Mössbauer; Ionic structures; Hydrogen bonds; Supramolecular architectures; Tetrahedral SnMe₂Cl₂

Domaines: Matériaux; Chimie de coordination

Waly Diallo, Kochikpa Y. A. Okio, Libasse Diop, Amadou-Lamine Diop, Umberto Russo, et al.. Some new sulfato and hydrogenosulfato adducts : synthesis, infrared and Mössbauer studies. Scientific Study and Research: Chemistry and Chemical Engineering, Biotechnology, Food Industry, 2010, 11 (2), pp.219-226. ⟨hal-00473009⟩