A One-Pot Synthesis of a 243-Allyl Dendrimer under Ambient Conditions

Catia Ornelas (1) , Jaime Ruiz Aranzaes (1) , Eric Cloutet (2, 3) , Didier Astruc (1)

1 ISM - Institut des Sciences Moléculaires
2 LCPO - Laboratoire de Chimie des polymères organiques
3 Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies

Hydrosilylation of a nonaallyl dendritic core using HSi(Me)2Cl followed by reaction with a phenolate dendronic brick bearing three allyl groups, followed by repetition of this sequence of reactions twice, allows a one-pot synthesis of a 243-allyl dendrimer under ambient conditions.

Domaines: Polymères

Catia Ornelas, Jaime Ruiz Aranzaes, Eric Cloutet, Didier Astruc. A One-Pot Synthesis of a 243-Allyl Dendrimer under Ambient Conditions. Organic Letters, 2006, 8 (13), pp.2751-2753. ⟨10.1021/ol060811t⟩. ⟨hal-00399008⟩