Hydrogen sorption properties of magnesium particles decorated with metallic nanoparticles as catalyst

Annaïg Denis (1) , Elisabeth Sellier (2) , Cyril Aymonier (1) , Jean-Louis Bobet (1)

1 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux
2 Centre de Ressources en Microscopie Electronique et Microanalyse

Both hydrogen absorption and desorption, in the range 200–300 and 260–330 °C, respectively, of magnesium particles decorated with metallic nanoplots elaborated by Supercritical Fluid Chemical process are studied. The absorption data are fitted using Avrami–Erofeev model to first order. Unexpectively, magnesium decorated with copper nanoparticles lead to relatively high rates of sorption (absorption rate at 300 °C and desorption rate at 330 °C of about 0.4 wt%H min⁻¹) but its activation energy remains high (70 kJ mol⁻¹). The presence at the interface of MgCu₂, acting as a chemical link between the nanoCu and the magnesium particle could be responsible for such behavior. Palladium nanoparticles react with magnesium during cycling so that the catalytic effect is decreasing with cycling and finally does not exist anymore after 10 cycles. Finally, the best results are obtained for the nanocomposite of magnesium with nickel nanoparticles for which the sorption rates are comparable with the ones obtained for optimized BM samples with catalysts, but with a lower energy cost of the process.

Mots clés: Nanoparticles; Magnesium; Supercritical fluid chemical deposition; Hydrogen sorption; Kinetics

Domaines: Matériaux

Annaïg Denis, Elisabeth Sellier, Cyril Aymonier, Jean-Louis Bobet. Hydrogen sorption properties of magnesium particles decorated with metallic nanoparticles as catalyst. Journal of Alloys and Compounds, 2009, 476 (1-2), pp.152-159. ⟨10.1016/j.jallcom.2008.09.016⟩. ⟨hal-00379174⟩