Dielectric relaxation in tetragonal tungsten bronze ceramics

Virginie Hornebecq (1) , Catherine Elissalde (1) , V. Porokhonskyy (2) , Viktor Bovtun (2) , J. Petzelt (2) , I. Gregora (2) , Mario Maglione (1) , Jean Ravez (1)

1 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux
2 Institute of Physics

Ferroelectric tantalates with the tetragonal tungsten bronze (TTB) type structure were studied over a wide frequency range from 102 to 109 Hz. Complementary microwave measurements at 36 GHz and micro-Raman experiments were performed in order to extend the dielectric study. A high frequency relaxation was observed above 108 Hz and fitted to the Cole–Cole formula. Different qualitative models are proposed to explain the understanding of the origin of the high frequency relaxation in ferroelectrics. Among these, polar clusters of ferroelectric active off-centred Ta5+ ions are considered.

Mots clés: Ceramics; Oxides; Raman spectroscopy; Dielectric properties; Ferroelectricity

Domaines: Matériaux

Virginie Hornebecq, Catherine Elissalde, V. Porokhonskyy, Viktor Bovtun, J. Petzelt, et al.. Dielectric relaxation in tetragonal tungsten bronze ceramics. Journal of Physics and Chemistry of Solids, 2003, 64 (3), pp.471-476. ⟨10.1016/S0022-3697(02)00342-6⟩. ⟨hal-00258318⟩