Octadecanuclear cluster or 1D polymer with [{ML}2Nb(CN)8]n motifs as a function of {ML} (M = Ni(II), n = 6; M = Mn(II), n = ¥; L = macrocycle)

Rabindranath Pradhan (1) , Cédric Desplanches (1) , Philippe Guionneau (1) , Jean-Pascal Sutter (1)

1 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux

A nanosized octadecaheteronuclear aggregate, [{NiL2}12{Nb-(CN)8}6(H2O)6], and a 1-D coordination polymer, [{MnL1}2{Nb-(CN)8}(H2O)]¥, have been obtained by self-assembly between the octacyanometalate {Nb(CN)8}4- and {ML}2+ complexes...

Mots clés: Polymer; Cluster; Octadecanuclear; Macrocycle

Domaines: Matériaux

Rabindranath Pradhan, Cédric Desplanches, Philippe Guionneau, Jean-Pascal Sutter. Octadecanuclear cluster or 1D polymer with [{ML}2Nb(CN)8]n motifs as a function of {ML} (M = Ni(II), n = 6; M = Mn(II), n = ¥; L = macrocycle). Inorganic Chemistry, 2003, 42 (21), pp.6607-6609. ⟨10.1021/ic034628x⟩. ⟨hal-00173324⟩