Two new pseudohalide bridged di- and poly-nuclear copper(II) complexes: synthesis, crystal structures and magnetic studies

Soma Sen (1) , Samiran Mitra (1) , David L. Hughes (2) , Georgina M. Rosair (1) , Cédric Desplanches (3)

1 Department of Chemistry
2 School of Chemical Sciences and Pharmacy
3 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux

Two new pseudohalide bridged di- and poly-nuclear copper(II) complexes [Cu2(L)2(μ1,1-N3)2] (1), [Cu(L)(μ1,3-NCS)]n (2), [LH = C6H5C(O)NHNdouble bond; length as m-dashC(CH3)C5H4N] have been synthesised and characterised by elemental analysis, IR and UV–Vis spectral studies...

Mots clés: Copper(II) complexes; Tridentate hydrazone ligand; Crystal structures; Magnetic studies

Domaines: Matériaux

Soma Sen, Samiran Mitra, David L. Hughes, Georgina M. Rosair, Cédric Desplanches. Two new pseudohalide bridged di- and poly-nuclear copper(II) complexes: synthesis, crystal structures and magnetic studies. Polyhedron, 2007, 26 (8), pp.1740-1744. ⟨10.1016/j.poly.2006.12.015⟩. ⟨hal-00148864⟩