A novel approach to prepare Poly(3,4-ethylenedioxythiophene) nanoribbons between V2O5 layers by microwave irradiation

A. Vadivel Murugan (1) , Chai-Won Kwon (2) , Guy Campet (2) , B. B. Kale (1) , A. B. Mandale (3) , S. R. Sainker (3) , Chinnakonda S. Gopinath (3) , K. Vijayamohanan (3)

1 C-MET - Centre for Materials for Electronics Technology
2 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux
3 Catalysis Division

Rapid synthesis of poly(3,4-ethylenedioxythiophene) (PEDOT) nanoribbons interleaved between the layers of crystalline V2O5 is achieved for the first time under microwave irradiation via the redox intercalative polymerization reaction of 3,4-ethylenedioxythiophene (EDOT) monomer and crystalline V2O5 at different time intervals...

Mots clés: Electric conductivity; Cyclic voltammetry; Hybrid organic-inorganic materials; Nanocomposites; Polymer morphology; Conducting polymers; Electric potential; Poly(3; 4-ethylenedioxythiophene); Lithium; Vanadium oxides

Domaines: Matériaux

A. Vadivel Murugan, Chai-Won Kwon, Guy Campet, B. B. Kale, A. B. Mandale, et al.. A novel approach to prepare Poly(3,4-ethylenedioxythiophene) nanoribbons between V2O5 layers by microwave irradiation. Journal of Physical Chemistry B, 2004, 108 (30), pp.10736 -10742. ⟨10.1021/jp048859g⟩. ⟨hal-00145601⟩