Spin transfer and magnetic interaction via phosphorus in nitronyl nitroxide radical-substituted triphenylphosphine derivatives

Corinne Rancurel (1) , Henrike Heise (2) , Frank H. Köhler (2, 3) , Ulrich Schatzschneider (4) , Eva Rentschler (3) , Jose Vidal-Gancedo (5) , Jaume Veciana (5) , Jean-Pascal Sutter (1)

1 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux
2 Anorganisch-chemisches Institut
3 Max‐Planck‐Institut für Bioanorganische Chemie
4 CALTECH - California Institute of Technology
5 ICMAB - Institut de Ciència de Materials de Barcelona

The magnetic behavior of polyradicals is usually understood on the basis of the spin polarization scheme displayed by the molecules...

Mots clés: Phosphines; Nitroxides; Ferromagnetic exchange; Radicals; Density functional theory; Spin polarization; Heterocyclic compounds; Crystal structure; Exchange interaction; Molecular structure; Electron spin density; NMR; Electron spin resonance

Domaines: Matériaux

Corinne Rancurel, Henrike Heise, Frank H. Köhler, Ulrich Schatzschneider, Eva Rentschler, et al.. Spin transfer and magnetic interaction via phosphorus in nitronyl nitroxide radical-substituted triphenylphosphine derivatives. Journal of Physical Chemistry A, 2004, 108 (27), pp.5903-5914. ⟨10.1021/jp049730+⟩. ⟨hal-00142736⟩