Palladium chemistry in anhydrous HF/AsF5 superacid medium

Zoran Mazej (1) , Primo Benki (1) , Alain Tressaud (2) , Boris Zemva (1)

1 Department of Inorganic Chemistry and Technology
2 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux

Pd metal dissolves in anhydrous HF (aHF) acidified with AsF5 in the presence of F2 at ~ 298 K to give a blue-green solution from which green Pd(AsF6)2 can be isolated...

Mots clés: Palladium; Fluorine; Superacids; Structure elucidation; Magnetic properties

Domaines: Matériaux

Zoran Mazej, Primo Benki, Alain Tressaud, Boris Zemva. Palladium chemistry in anhydrous HF/AsF5 superacid medium. European Journal of Inorganic Chemistry, 2004, 9, pp.1827-1834. ⟨10.1002/ejic.200300681⟩. ⟨hal-00139228⟩