A novel manganese(III) quadridentate Schiff-base dimeric complex: synthesis, crystal structure and magnetic properties

Ruma Karmakar (1) , Chirantan Roy Choudhury (1) , Georges Bravic (2) , Jean-Pascal Sutter (2) , Samiran Mitra (1)

1 Department of Chemistry
2 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux

One new dimeric manganese(III) complex [MnL(H2O)]2(ClO4)2 · H2O (1) where [L=N,N′-bis(2-hydroxyacetophenylidene)-1,2-diaminopropane] has been synthesised and characterised by spectroscopic and electrochemical study, and the single crystal structure of the complex was determined...

Mots clés: Dimeric complex; Manganese(III); Crystal structure; Ferromagnetic behaviour

Domaines: Matériaux

Ruma Karmakar, Chirantan Roy Choudhury, Georges Bravic, Jean-Pascal Sutter, Samiran Mitra. A novel manganese(III) quadridentate Schiff-base dimeric complex: synthesis, crystal structure and magnetic properties. Polyhedron, 2004, 23 (6), pp.949-954. ⟨10.1016/j.poly.2003.12.012⟩. ⟨hal-00137565⟩