Crystal growth of new perovskite and perovskite related iridates: Ba3LiIr2O9, Ba3NaIr2O9, and Ba3.44K1.56Ir2O10

Seung-Joo Kim (1) , Mark D. Smith (1) , Jacques Darriet (2) , Hans-Conrad Zur Loye (1)

1 Department of Chemistry and Biochemistry [Columbia, South Carolina]
2 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux

Single crystals of Ba3LiIr2O9, Ba3NaIr2O9, and Ba3.44K1.56Ir2O10 were grown from hydroxide fluxes. Ba3LiIr2O9 and Ba3NaIr2O9 form in the 6H–BaTiO3 or triple perovskite structure, which is derived from the hexagonal and cubic stacking of [AO3] layers...

Mots clés: Oxides; Crystal growth; Magnetic properties; Crystal structure

Domaines: Matériaux

Seung-Joo Kim, Mark D. Smith, Jacques Darriet, Hans-Conrad Zur Loye. Crystal growth of new perovskite and perovskite related iridates: Ba3LiIr2O9, Ba3NaIr2O9, and Ba3.44K1.56Ir2O10. Journal of Solid State Chemistry, 2004, 177 (4-5), pp.1493-1500. ⟨10.1016/j.jssc.2003.11.037⟩. ⟨hal-00137506⟩