Tentative mechanisms for acrylate intercalation and in situ polymerization in nickel-based layered double hydroxides

Christophe Vaysse (1) , Liliane Guerlou-Demourgues (1) , Claude Delmas (1) , Etienne Duguet (1)

1 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux

New hybrid organic-inorganic materials, based on polyacrylate macromolecules intercalated into Layered Double Hydroxides (LDHs) deriving from Ni(OH)2, were prepared through an original route made of successive redox exchange reactions (chimie douce synthesis)...

Mots clés: Layered double hydroxides; Hydrotalcite; Chimie douce; Intercalation; Oxometalate; Grafting; EXAFS; Acrylate; Interslab polymerisation; Hybride organic-inorganic materials

Domaines: Matériaux

Christophe Vaysse, Liliane Guerlou-Demourgues, Claude Delmas, Etienne Duguet. Tentative mechanisms for acrylate intercalation and in situ polymerization in nickel-based layered double hydroxides. Macromolecules, 2004, 37 (1), pp.45-51. ⟨10.1021/ma025882w⟩. ⟨hal-00136203⟩