Photomagnetism in cyano-bridged hexanuclear clusters [MnII(bpy)2]4[MIV(CN)8]2.xH2O (M = Mo, x = 14, and M = W, x = 9)

Corine Mathonière (1) , Robert Podgajny (2) , Philippe Guionneau (1) , Christine Labrugère (1) , Barbara Sieklucka (2)

1 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux
2 Faculty of Chemistry

The magnetic and photomagnetic properties of two cyano-bridged, [Mn(bpy)2]4[Mo(CN)8]2·14H2O (1) and [Mn(bpy)2]4[W(CN)8]2·9H2O (2) (bpy = 2,2'-bipyridyl), hexanuclear clusters (hereafter named MnII4MIV2) have been investigated...

Mots clés: Photomagnetism; Photoinduced magnetic-properties; Crystal structure; Octacyanotungstate(V) ion; Molecular oxygen; Ground state; Complexes; Photochemistry; Luminescence; Reactivity; Photolysis

Domaines: Matériaux

Corine Mathonière, Robert Podgajny, Philippe Guionneau, Christine Labrugère, Barbara Sieklucka. Photomagnetism in cyano-bridged hexanuclear clusters [MnII(bpy)2]4[MIV(CN)8]2.xH2O (M = Mo, x = 14, and M = W, x = 9). Chemistry of Materials, 2005, 17 (2), pp.442-449. ⟨10.1021/cm048785l⟩. ⟨hal-00021206⟩