Precipitation dynamics of zinc sulfide multi-scale agglomerates

Frédéric Gruy (1, 2) , Mohamed Kamal Mekki Berrada (1, 2) , Michel Cournil (1, 2, 3)

1 GENERIC-ENSMSE - Département Géochimie, environnement, écoulement, réacteurs industriels et cristallisation
2 SPIN-ENSMSE - Centre Sciences des Processus Industriels et Naturels
3 LPMG-EMSE - Laboratoire des Procédés en Milieux Granulaires

Homogeneous precipitation of zinc sulfide from thioacetamide decomposition in presence of zinc sulfate in acid solution results in the formation of four-scale agglomerates. We present here experimental results relative to the monitoring of several physicochemical (pH, electrical conductivity, concentration in sulfide ions, turbidity) and morphological (agglomerate shape and size) parameters throughout the precipitation process. From these parameters essential characteristics of the precipitation process can be determined, especially the supersaturation level and the precipitated product mass. From this information and with the help of microphotographs of samples withdrawn at different stages of the precipitation, it is possible to formulate a new mechanism of zinc sulfide precipitation. In particular the nature of the different agglomeration scales is elucidated as well their succession in time.

Mots clés: precipitation; agglomeration; zinc sulfide; multi-scale agglomerates

Domaines: Génie des procédés

Frédéric Gruy, Mohamed Kamal Mekki Berrada, Michel Cournil. Precipitation dynamics of zinc sulfide multi-scale agglomerates. AIChE Journal, 2009, 55 (10), pp.2553-2562. ⟨10.1002/aic.11870⟩. ⟨hal-00438798⟩