A new and convenient way fot the synthesis of strong non-ionic bases

Marc Taillefer (1) , Jean-Noël Null Volle (1) , Nicolas Rahier (1) , Aurélien Hameau (1)

1 ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier

Various strong non-ionic phosphazene bases were obtained by a new, efficient and very simple way involving the lithium phosphonium azayldiide Ph3P=NLi (2) as a precursor.

Mots clés: Ph3P=NLi; azayldiide; strong non-ionic bases; phosphorus halides; phosphazene; Schwesinger

Domaines: Chimie organique

Marc Taillefer, Jean-Noël Null Volle, Nicolas Rahier, Aurélien Hameau. A new and convenient way fot the synthesis of strong non-ionic bases. Chemical Communications, 2006, 30, pp.3238-3239. ⟨10.1039/b603677e⟩. ⟨hal-00186074⟩