Rhodium-Catalyzed Oxidative C−H Arylation of 2-Arylpyridine Derivatives via Decarbonylation of Aromatic Aldehydes

Qi Shuai (1) , Luo Yang (1) , Xiangyu Guo (1) , Olivier Baslé (1) , Chao-Jun Li (1)

1 Department of Chemistry [Montréal]

A new concept for aryl−aryl coupling that involves oxidative decarbonylative coupling of aryl C−H bonds and readily available aldehydes has been developed, achieving the aryl−aryl union with complete control of reaction sites.

Mots clés: Arylation; Hydrocarbons; Cross coupling reaction; Aldehydes; Aromatic compounds

Domaines: Chimie de coordination

Qi Shuai, Luo Yang, Xiangyu Guo, Olivier Baslé, Chao-Jun Li. Rhodium-Catalyzed Oxidative C−H Arylation of 2-Arylpyridine Derivatives via Decarbonylation of Aromatic Aldehydes. Journal of the American Chemical Society, 2010, 132 (35), pp.12212-12213. ⟨10.1021/ja105396b⟩. ⟨hal-03652863⟩